Boyles Law

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In

1660 Robert Boyle found out experimentally the change in volume of a given sample of fou with it room temperature. From his observations he formulated a generalisation known as Boyle's Law, it states that:


At constant temperature, the volume of a fixed mass of gas is inversely proportional to its pressure.

If the pressure is doubled, the volume is halved.



The Boyle's Law may be expressed mathematically as


V 1/P

V = k x 1/P


Where k is a proportionality constant.


PV = K


If P1, V1 are the initial pressure and volume of a given sample of gas and P2, V2 the chenged pressure and volume,

we can write


P1 V1 = k = P2 V2

P1 V1 = P2 V2


This relationship is useful for the determination of the volume of a gas at any pressure, if iis volume at any other pressure is known. "full'


Isotherm plot

Example :



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